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Purity, formulations and chromatography: GCSE Combined Science Chemistry practice questions

Foundation and Higher · Grade 4

A second set of questions on purity, formulations and chromatography. They are different from the ones on the topic page. Try each, then open the answer and compare your working.

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Question 1 Medium

What name is given to a mixture designed as a useful product, made with carefully measured amounts?

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Answer: formulation

  1. Paints and medicines are designed mixtures.
  2. They are formulations.

Question 2 Medium

Should the solvent level in the beaker be above or below the pencil line at the start?

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Answer: below

  1. If the spots were under the solvent they would dissolve.
  2. The solvent level is below the line.

Question 3 Hard

A spot moves 2.8 cm. The solvent front moves 8.0 cm. Calculate the Rf value.

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Answer: 0.35

  1. Rf = 2.8 ÷ 8.0.
  2. Rf = 0.35.

Question 4 Hard

A compound has an Rf value of 0.60. The solvent front moves 7.5 cm. How far does the compound move? Give your answer in cm.

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Answer: 4.5 cm

  1. Distance moved by substance = Rf × distance moved by solvent.
  2. 0.60 × 7.5 = 4.5 cm.

Question 5 Hard

A solid melts between 95 °C and 99 °C. Is it pure or impure?

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Answer: impure

  1. A pure solid melts at one sharp temperature.
  2. Melting over a range shows it is impure.

Question 6 Hard

Which of these is a formulation: pure water, a tin of paint or a copper wire?

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Answer: a tin of paint

  1. A formulation is a designed mixture.
  2. Paint is a mixture of several components with a purpose.

Question 7 Hard

Two spots in the same solvent have the same Rf value. What might this suggest about the two substances?

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Answer: they are the same substance

  1. Different compounds usually have different Rf values.
  2. The same Rf suggests the same substance.

Question 8 Hard

A chromatogram of an ink shows 3 spots. What is the smallest number of substances in the ink?

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Answer: 3

  1. Each spot is a different substance.
  2. There are at least 3 substances.

Quick checks

Short questions with options. Choose one before you open the answer.

Check 1

What does pure mean in chemistry?

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A single element or compound, not mixed with any other substance.

Check 2

How does melting point show whether a substance is pure?

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A pure substance melts at one sharp temperature. A mixture melts over a range.

Check 3

Does an impure substance usually melt at a lower or higher temperature than the pure one?

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Lower, and over a range.

Check 4

What is a formulation?

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A mixture designed as a useful product, made with carefully measured quantities of each component.

Check 5

Give three examples of formulations.

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Fuels, cleaning agents, paints, medicines, alloys, fertilisers and foods.

Check 6

What is chromatography used for?

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To separate mixtures of soluble substances and help identify them.

Check 7

In paper chromatography, what is the stationary phase?

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The paper.

Check 8

In paper chromatography, what is the mobile phase?

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The solvent.

Check 9

Why is the start line drawn in pencil?

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Pencil does not dissolve in the solvent. Ink would run.

Check 10

Why must the solvent level be below the start line?

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So the spots do not dissolve into the solvent in the beaker.

Check 11

What does one spot on a chromatogram show?

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The sample is a pure substance.

Check 12

What does more than one spot show?

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The sample is a mixture of at least that many substances.

Check 13

How do you identify a substance on a chromatogram?

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Compare its position and colour with known substances run on the same paper.

Check 14

What is the formula for the Rf value?

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Rf = distance moved by substance ÷ distance moved by solvent.

Check 15

Where do you measure the substance distance to?

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The centre of the spot, from the start line.

Check 16

What is the unit of Rf?

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It has no unit.

Check 17

What is the range of possible Rf values?

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Between 0 and 1.

Check 18

Why can an Rf value help identify a compound?

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Different compounds usually have different Rf values in the same solvent.

Check 19

Why do you mark the solvent front straight away?

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The solvent evaporates from the paper, so you would lose the position.

Check 20

Why do substances move different distances?

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They spend different amounts of time dissolved in the mobile phase and held on the stationary phase.

Check 21

Is carton orange juice pure in the chemical sense?

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No. It is a mixture of several substances, so it is not pure in chemistry.

Check 22

Can two different substances have the same Rf?

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Yes, so Rf alone cannot prove the identity. Use more than one test.

Check 23

What can simple distillation do in the inks practical?

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Separate the solvent (water) from the dyes in the ink.

Check 24

What happens to the Rf value if the solvent changes?

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It changes. Only compare Rf values for the same solvent.

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