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The Haber process and fertilisers: GCSE Combined Science Chemistry practice questions

Foundation and Higher · Grade 6

A second set of questions on the Haber process and fertilisers. They are different from the ones on the topic page. Try each, then open the answer and compare your working.

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Question 1 Medium

How is ammonia separated from the unreacted gases?

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Answer: by cooling it

  1. Ammonia has a higher boiling point than nitrogen and hydrogen.
  2. Cooling makes the ammonia condense to a liquid.

Question 2 Medium

What symbol shows that the reaction is reversible?

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Answer: ⇌

  1. A reversible reaction has arrows both ways.
  2. The symbol is ⇌.

Question 3 Hard

Does the iron catalyst change the position of equilibrium?

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Answer: no

  1. A catalyst speeds up both forward and backward reactions equally.
  2. So it does not change the position of equilibrium.

Question 4 Hard

The forward reaction is exothermic. What happens to the yield of ammonia at equilibrium if the temperature is raised?

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Answer: it decreases

  1. Raising the temperature favours the endothermic direction.
  2. The backward reaction is endothermic, so less ammonia is made.

Question 5 Hard

In N₂ + 3H₂ ⇌ 2NH₃, how many molecules of gas are on the left-hand side?

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Answer: 4

  1. Add the numbers in front of the left-hand formulae.
  2. 1 + 3 = 4.

Question 6 Hard

Why is a pressure much higher than 200 atmospheres not used?

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Answer: it is too expensive

  1. High pressure needs strong pipes and powerful pumps.
  2. These are expensive and dangerous.

Question 7 Hard

Calculate the mass of ammonia (NH₃) made from 28 g of nitrogen (N₂). Ar: N = 14, H = 1. Give your answer in g.

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Answer: 34 g

  1. 28 g of N₂ is 1 mol.
  2. 1 mol of N₂ makes 2 mol of NH₃, which is 2 × 17 = 34 g.

Question 8 Hard

A plant should make 50 tonnes of ammonia but makes 12 tonnes. Calculate the percentage yield.

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Answer: 24%

  1. Percentage yield = actual ÷ maximum × 100.
  2. 12 ÷ 50 × 100 = 24%.

Quick checks

Short questions with options. Choose one before you open the answer.

Check 1

What is the Haber process used to make?

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Ammonia.

Check 2

What is the balanced equation for the Haber process?

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N₂ + 3H₂ ⇌ 2NH₃.

Check 3

Where does the nitrogen come from?

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The air.

Check 4

Where does the hydrogen come from?

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Natural gas (methane).

Check 5

What temperature is used in the Haber process?

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About 450 °C.

Check 6

What pressure is used in the Haber process?

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About 200 atmospheres.

Check 7

What catalyst is used in the Haber process?

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Iron.

Check 8

What does the catalyst do?

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Speeds up the reaction. It does not change the yield.

Check 9

Is the forward reaction in the Haber process exothermic or endothermic?

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Exothermic.

Check 10

Why is a lower temperature not used?

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The reaction would be too slow.

Check 11

Why is a higher temperature not used?

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It would lower the yield of ammonia.

Check 12

Why does a high pressure increase the yield?

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There are fewer gas molecules on the right (2) than on the left (4).

Check 13

Why is a much higher pressure not used?

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Equipment is expensive and dangerous at very high pressure.

Check 14

How is ammonia separated from the unreacted gases?

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It is cooled and condenses to a liquid.

Check 15

What happens to unreacted nitrogen and hydrogen?

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They are recycled into the reactor.

Check 16

What is the formula of ammonia?

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NH₃.

Check 17

What is ammonia used to make?

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Fertilisers, such as ammonium nitrate.

Check 18

Why do farmers use fertilisers?

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They supply nitrogen, which plants need to grow, so crop yields rise.

Check 19

Why is too much fertiliser a problem?

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It can wash into rivers and harm wildlife.

Check 20

What ratio of nitrogen to hydrogen is used?

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1 : 3.

Check 21

What does dynamic equilibrium mean?

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Forward and backward reactions occur at the same rate, so amounts stay constant.

Check 22

What do NPK fertilisers contain? (Separate Chemistry only)

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Compounds of nitrogen, phosphorus and potassium.

Check 23

How is nitrogen separated from the air?

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By fractional distillation of liquid air.

Check 24

Does a catalyst change the position of equilibrium?

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No.

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