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Reversible reactions and equilibrium: GCSE Combined Science Chemistry practice questions
Foundation and Higher · Grade 6
A second set of questions on reversible reactions and equilibrium. They are different from the ones on the topic page. Try each, then open the answer and compare your working.
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Question 1 Medium
The forward reaction is endothermic. What happens to the yield of products if the temperature is increased?
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Answer: it increases
A higher temperature favours the endothermic direction.
So the yield of products increases.
Question 2 Medium
Does a catalyst change the yield at equilibrium? Answer yes or no.
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Answer: no
A catalyst speeds up both directions equally.
So the yield is unchanged.
Question 3 Medium
In 2SO₂ + O₂ ⇌ 2SO₃, how many gas molecules are on the left side?
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Answer: 3
There are 2 SO₂ molecules and 1 O₂ molecule.
2 + 1 = 3.
Question 4 Medium
A reaction at equilibrium is exothermic in the forward direction. What happens to the yield of products if the temperature is increased?
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Answer: it decreases
A higher temperature favours the endothermic direction.
The reverse reaction is endothermic, so the yield of products decreases.
Question 5 Hard
For H₂ + I₂ ⇌ 2HI there are the same number of gas molecules on each side. Explain what happens to the position of equilibrium when the pressure is increased.
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Answer: it does not change because there are the same number of gas molecules on each side
2 molecules on the left and 2 on the right.
So pressure has no effect on the position.
Question 6 Hard
N₂O₄ ⇌ 2NO₂ is endothermic in the forward direction. What happens to the amount of NO₂ if the temperature is lowered?
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Answer: it decreases
A lower temperature favours the exothermic direction.
The reverse is exothermic, so the position shifts left and there is less NO₂.
Question 7 Hard
Explain why the Haber process uses a compromise temperature of about 450 °C.
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Answer: a lower temperature gives a higher yield but the rate would be too slow
A lower temperature gives a higher yield.
But the rate is too slow, so a compromise is used.
Question 8 Hard
In a closed container, the equilibrium CO + 2H₂ ⇌ CH₃OH is established. More H₂ is added. State and explain the effect on the position of equilibrium.
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Answer: it shifts to the right to use up the extra hydrogen
Increasing the concentration of a reactant opposes the change by using it up.
The position shifts to the right.
Question 9 Medium
On a graph of concentration against time for a reversible reaction in a closed container, both lines become flat after 6 minutes. What does this show?
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Answer: equilibrium has been reached
Flat lines mean the amounts are no longer changing.
The forward and reverse rates are equal, so equilibrium has been reached.
Question 10 Hard
A student says that at equilibrium the reactions have stopped because the concentrations do not change. Explain why the student is wrong.
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Answer: both reactions are still happening at the same rate
Both reactions are still happening.
They happen at the same rate, so there is no overall change.
Quick checks
Short questions with options. Choose one before you open the answer.
Check 1
What does ⇌ mean?
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A reversible reaction.
Check 2
What is a closed system?
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One in which nothing can enter or leave.
Check 3
What is dynamic equilibrium?
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The forward and reverse reactions happen at the same rate in a closed system.
Check 4
Are the concentrations equal at equilibrium?
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Not necessarily. They are constant.
Check 5
What does Le Chatelier’s principle say?
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A system at equilibrium moves to oppose a change.
Check 6
What happens if reactant concentration is increased?
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The equilibrium shifts to the right.
Check 7
What happens if pressure increases?
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The equilibrium shifts to the side with fewer gas molecules.
Check 8
What happens if temperature increases?
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The equilibrium shifts in the endothermic direction.
Check 9
What happens if temperature decreases?
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The equilibrium shifts in the exothermic direction.
Check 10
What is the effect of a catalyst on the position of equilibrium?
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None.
Check 11
What is the effect of a catalyst on the time to reach equilibrium?
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It is shorter.
Check 12
What colour change shows hydrated copper sulfate being heated?
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Blue to white.
Check 13
What is the position of equilibrium?
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The relative amounts of reactants and products at equilibrium.
Check 14
If the forward reaction is exothermic, what is the reverse?
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Endothermic.
Check 15
Why is a compromise temperature used in the Haber process?
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A low temperature gives a higher yield but the rate is too slow.
Check 16
What is a reversible reaction?
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One where the products can react to make the reactants again.
Check 17
What colour is anhydrous copper sulfate?
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White.
Check 18
What happens when water is added to white copper sulfate?
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It turns blue and gives out heat.
Check 19
What happens to the amounts of reactants and products at equilibrium?
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They stay constant.
Check 20
Why is it called a dynamic equilibrium?
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Both the forward and reverse reactions are still happening.
Check 21
What does it mean if the position of equilibrium is to the right?
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There are more products than reactants.
Check 22
What happens if a product is removed from an equilibrium mixture?
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The position shifts right to make more product.
Check 23
What happens to the position of equilibrium if the pressure decreases?
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It shifts to the side with more gas molecules.
Check 24
Does pressure change the position if both sides have equal gas molecules?
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No.
Check 25
How many gas molecules are on the left of N₂ + 3H₂ ⇌ 2NH₃?
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Four.
Check 26
Why does a graph of concentration against time go flat at equilibrium?
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The forward and reverse reactions are still happening at the same rate, so the amounts stop changing.
Keep going with Reversible reactions and equilibrium