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Titrations and their calculations: GCSE Combined Science Chemistry practice questions
Higher tier content · Grade 8
A second set of questions on titrations and their calculations. They are different from the ones on the topic page. Try each, then open the answer and compare your working.
More questions
Question 1 Medium
25.0 cm³ of 0.100 mol/dm³ NaOH needs 20.0 cm³ of hydrochloric acid. Calculate the concentration of the acid in mol/dm³.
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Answer: 0.125 mol/dm³
Moles of NaOH = 0.100 × 0.0250 = 0.00250.
Concentration of HCl = 0.00250 ÷ 0.0200 = 0.125.
Question 2 Medium
Convert a concentration of 0.125 mol/dm³ of HCl into g/dm³. Mr of HCl = 36.5. Give your answer to 3 significant figures.
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Answer: 4.56 g/dm³
Multiply mol/dm³ by Mr.
0.125 × 36.5 = 4.5625.
Question 3 Medium
Calculate the moles of sodium hydroxide in 25.0 cm³ of 0.200 mol/dm³ NaOH.
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Answer: 0.00500 mol
25.0 cm³ = 0.0250 dm³.
Moles = 0.200 × 0.0250 = 0.00500.
Question 4 Medium
A solution of NaOH has a concentration of 0.250 mol/dm³. Calculate its concentration in g/dm³. Mr of NaOH = 40.
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Answer: 10.0 g/dm³
Multiply mol/dm³ by Mr.
0.250 × 40 = 10.0.
Question 5 Hard
H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O. 25.0 cm³ of 0.200 mol/dm³ NaOH needs 20.0 cm³ of H₂SO₄. Calculate the concentration of the acid in mol/dm³.
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Answer: 0.125 mol/dm³
Moles of NaOH = 0.200 × 0.0250 = 0.00500.
Moles of H₂SO₄ = 0.00250.
Concentration = 0.00250 ÷ 0.0200 = 0.125.
Question 6 Hard
20.0 cm³ of 0.0500 mol/dm³ sulfuric acid is neutralised by NaOH solution. Calculate the moles of NaOH needed. H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O
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Answer: 0.00200 mol
Moles of H₂SO₄ = 0.0500 × 0.0200 = 0.00100.
The ratio is 1 : 2, so NaOH = 0.00200.
Question 7 Hard
25.0 cm³ of potassium hydroxide is neutralised by 15.0 cm³ of 0.200 mol/dm³ HCl. Calculate the concentration of the potassium hydroxide in g/dm³. Mr of KOH = 56.
A student says a rough titre should be included in the mean. Explain why this is wrong.
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Answer: it is less accurate because the acid was added quickly
The rough titre is only used to find the approximate end-point.
It is less accurate because the acid is added quickly.
Question 9 Medium
Calculate the mean of the concordant titres 15.10, 15.20 and 15.15 cm³.
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Answer: 15.15 cm³
(15.10 + 15.20 + 15.15) ÷ 3.
45.45 ÷ 3 = 15.15.
Question 10 Hard
25.0 cm³ of sulfuric acid is neutralised by 30.0 cm³ of 0.100 mol/dm³ sodium hydroxide. H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O. Calculate the concentration of the acid in mol/dm³.
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Answer: 0.0600 mol/dm³
Moles of NaOH = 0.100 × 0.0300 = 0.00300.
Moles of H₂SO₄ = 0.00300 ÷ 2 = 0.00150.
Concentration = 0.00150 ÷ 0.0250 = 0.0600.
Quick checks
Short questions with options. Choose one before you open the answer.
Check 1
What is a titration?
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A method to find the volumes of two solutions that exactly react.
Check 2
Which apparatus measures 25.0 cm³ accurately?
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A pipette.
Check 3
What does the burette measure?
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The volume of solution added.
Check 4
What is the end-point?
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The point where the indicator just changes colour.
Check 5
What is the titre?
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The volume added from the burette to reach the end-point.
Check 6
What does concordant mean?
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Results within 0.10 cm³ of each other.
Check 7
What should you do with the rough titration?
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Leave it out of the mean.
Check 8
What colour is phenolphthalein in alkali?
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Pink.
Check 9
What colour is methyl orange in acid?
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Red.
Check 10
Why not use universal indicator in a titration?
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The colour change is gradual.
Check 11
What is the equation for moles from concentration?
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Moles = concentration × volume in dm³.
Check 12
How many moles of NaOH react with 1 mole of H₂SO₄?
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2.
Check 13
How do you change mol/dm³ into g/dm³?
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Multiply by the relative formula mass.
Check 14
Why add the acid drop by drop near the end?
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To avoid overshooting the end-point.
Check 15
What do you do to cm³ before using it in a concentration calculation?
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Divide by 1000 to get dm³.
Check 16
What does a pipette do in a titration?
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It measures one fixed volume, such as 25.0 cm³, accurately.
Check 17
What is an indicator?
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A dye that changes colour to show the end-point.
Check 18
Why stand the flask on a white tile?
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The colour change is easier to see.
Check 19
Why rinse the burette with the acid before use?
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So that left-over water does not dilute the acid.
Check 20
What is an anomalous result?
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A result that does not fit with the others.
Check 21
What is the rough titration for?
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To find the approximate end-point.
Check 22
How many dm³ are in 25.0 cm³?
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0.0250 dm³.
Check 23
How do you find concentration in mol/dm³ from moles?
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Divide the moles by the volume in dm³.
Check 24
Where do you read the burette?
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At eye level, at the bottom of the meniscus.
Check 25
Why do you add the acid drop by drop near the end-point of a titration?
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So you do not overshoot, which would make the titre too large.